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1,7-octadiene
Sign in to save1,7-Octadiene is an organic compound with the formula . It is a colorless liquid that serves as a precursor to specialty polymers. It arises commercially by the dimerization of butadiene in the presence of hydrogen. Some of the 1,6-octadiene is also formed. 1,7-Octadiene can be converted to the diol by hydroformylation followed by hydrogenation of the dialdehyde. In a related process, 1,7-Octadiene undergoes hydrocyanation to give dinitrile, which can be hydrogenated to give 1,10-diaminodecane. thumb|center|Conversion of butadiene to 1,10-difunctionalized decanes ==Dimethyloctadienes== Structu
Chemical data
- Formula
- C8H14
- Molecular weight
- 110.2 g/mol
- IUPAC name
- octa-1,7-diene
- SMILES
- C=CCCCCC=C
- InChIKey
- XWJBRBSPAODJER-UHFFFAOYSA-N
- XLogP
- 3.5
- Polar surface area
- 0 Ų
- H-bond donors
- 0
- H-bond acceptors
- 0
- Formal charge
- 0
via PubChem
Wikidata facts
- Subclass of
- diene
- Mass
- 110.11
Show 3 more facts
- chemical formula
- C₈H₁₄
- canonical SMILES
- C=CCCCCC=C
- Commons category
- 1,7-Octadiene
Sources (1)
via Wikidata · CC0
~1 min read
Encyclopedic overview
4 sectionsContents
- Dimethyloctadienes
- Research
- References
- External links
1,7-Octadiene is an organic compound with the formula . It is a colorless liquid that serves as a precursor to specialty polymers. It arises commercially by the dimerization of butadiene in the presence of hydrogen. Some of the 1,6-octadiene is also formed. 1,7-Octadiene can be converted to the diol by hydroformylation followed by hydrogenation of the dialdehyde. In a related process, 1,7-Octadiene undergoes hydrocyanation to give dinitrile, which can be hydrogenated to give 1,10-diaminodecane. thumb|center|Conversion of butadiene to 1,10-difunctionalized decanes ==Dimethyloctadienes== Structurally related octadienes bearing two methyl groups are of commercial interest. Such compounds are produced by pyrolysis of pinane, which is abundantly available from terpentine or related wood-derived chemicals. thumb|center|Formation of dimethyloctadienes
==Research== The diene has also been the subject of many research papers. For example, with ethylene it undergoes a cross-enyne metathesis Diels–Alder reaction. It undergoes ring-closing metathesis to give cyclooctene. Plasma polymerized 1,7-octadiene films deposited on silica can produce particles with tuned hydrophobicity.
Excerpted from Wikipedia’s “1,7-octadiene” article, available under the CC BY-SA 4.0 licence.