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2-nitrobenzaldehyde
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2-nitrobenzaldehyde

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2-Nitrobenzaldehyde is an organic compound with the formula . It is one of three isomers of nitrobenzaldehyde. It contains a nitro group adjacent to the formyl group.

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  • Synthesis
  • Uses
  • References

2-Nitrobenzaldehyde is an organic compound with the formula . It is one of three isomers of nitrobenzaldehyde. It contains a nitro group adjacent to the formyl group.

==Synthesis== The nitration of benzaldehyde produces mostly 3-nitrobenzaldehyde. Partly for this reason, 2-nitrobenzaldehyde is prepared by indirect routes. The main routes to nitrobenzaldehyde begin with the nitration of styrene or cinnamic acid followed by the conversions of the resulting 2-nitrostyrene and 2-nitrocinnamic acids, respectively. Cinnamaldehyde can also be nitrated in high-yield to 2-nitrocinnamaldehyde. This compound is then oxidized to 2-nitrocinnamic acid, which is decarboxylated to the 2-nitrostyrene. The vinyl group can be oxidized in a number of different ways to yield 2-nitrobenzaldehyde.

Excerpted from Wikipedia’s “2-nitrobenzaldehyde” article, available under the CC BY-SA 4.0 licence.