hapticity
Sign in to save150px|right|thumb|Ferrocene contains two η5-[[cyclopentadienyl ligands]]
~7 min read
Article
8 sectionsContents
- History
- Historically important compounds where the ligands are described with hapticity
- Examples
- Electrons donated by "π-ligands" versus hapticity
- Changes in hapticity
- Hapticity vs. denticity
- Hapticity and fluxionality
- References
150px|right|thumb|Ferrocene contains two η5-[[cyclopentadienyl ligands]]
In coordination chemistry, hapticity is the coordination of a ligand to a metal center via an uninterrupted and contiguous series of atoms. The hapticity of a ligand is described with the Greek letter η ('eta'). For example, η2 describes a ligand that coordinates through 2 contiguous atoms. In general the η-notation only applies when multiple atoms are coordinated (otherwise the κ-notation is used). In addition, if the ligand coordinates through multiple atoms that are contiguous then this is considered denticity (not hapticity), and the κ-notation is used once again. When naming complexes care should be taken not to confuse η with μ ('mu'), which relates to bridging ligands.