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hapticity
EntityQ901811· pop 21· linked from 180 articles

150px|right|thumb|Ferrocene contains two η5-[[cyclopentadienyl ligands]]

~7 min read

Article

8 sections
Contents
  • History
  • Historically important compounds where the ligands are described with hapticity
  • Examples
  • Electrons donated by "π-ligands" versus hapticity
  • Changes in hapticity
  • Hapticity vs. denticity
  • Hapticity and fluxionality
  • References

150px|right|thumb|Ferrocene contains two η5-[[cyclopentadienyl ligands]]

In coordination chemistry, hapticity is the coordination of a ligand to a metal center via an uninterrupted and contiguous series of atoms. The hapticity of a ligand is described with the Greek letter η ('eta'). For example, η2 describes a ligand that coordinates through 2 contiguous atoms. In general the η-notation only applies when multiple atoms are coordinated (otherwise the κ-notation is used). In addition, if the ligand coordinates through multiple atoms that are contiguous then this is considered denticity (not hapticity), and the κ-notation is used once again. When naming complexes care should be taken not to confuse η with μ ('mu'), which relates to bridging ligands.

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