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hemiaminal
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hemiaminal

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Also known as alpha-amino alcohol

thumb|right|120px|Generic hemiaminal

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Hemiaminals
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Article

8 sections
Contents
  • Classification according to amine precursor
  • Addition of ammonia
  • Addition of primary amines
  • Addition of secondary amines: carbinolamines (hemiaminals) and bisaminomethanes
  • Hemiaminal ethers
  • Use in total synthesis
  • See also
  • References

thumb|right|120px|Generic hemiaminal

In organic chemistry, a hemiaminal (also carbinolamine) is a functional group or type of chemical compound that has a hydroxyl group and an amine attached to the same carbon atom: . R can be hydrogen or an alkyl group. Hemiaminals are intermediates in imine formation from an amine and a carbonyl by alkylimino-de-oxo-bisubstitution. Hemiaminals can be viewed as a blend of aminals and geminal diol. They are a special case of amino alcohols.

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