hexachlorobutadiene
Also known as HCBD, Hexachloro-1,3-butadiene, 1,3-Hexachlorobutadiene, Perchlorobutadiene
Hexachlorobutadiene, (often abbreviated as "HCBD") Cl2C=C(Cl)C(Cl)=CCl2, is a colorless liquid at room temperature that has an odor similar to that of turpentine. It is a chlorinated aliphatic diene with niche applications but is most commonly used as a solvent for other chlorine-containing compounds. Structurally, it has a 1,3-butadiene core, but fully substituted with chlorine atoms.
Research
292 papersvia PubMed
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Article
6 sectionsContents
- Synthesis
- Reactivity
- Applications
- Toxicity
- See also
- References
Hexachlorobutadiene, (often abbreviated as "HCBD") Cl2C=C(Cl)C(Cl)=CCl2, is a colorless liquid at room temperature that has an odor similar to that of turpentine. It is a chlorinated aliphatic diene with niche applications but is most commonly used as a solvent for other chlorine-containing compounds. Structurally, it has a 1,3-butadiene core, but fully substituted with chlorine atoms.
==Synthesis== Hexachlorobutadiene is primarily produced in chlorinolysis plants as a by-product in the production of carbon tetrachloride and tetrachloroethylene. Chlorinolysis is a radical chain reaction that occurs when hydrocarbons are exposed to chlorine gas under pyrolytic conditions. The hydrocarbon is chlorinated and the resulting chlorocarbons are broken down. This process is analogous to combustion, but with chlorine instead of oxygen.