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manganocene
Sign in to saveManganocene or bis(cyclopentadienyl)manganese(II) is an organomanganese compound with the formula [Mn(C5H5)2]n. It is a thermochromic solid that degrades rapidly in air. Although the compound is of little utility, it is often discussed as an example of a metallocene with ionic character.
Chemical data
- Formula
- C10H2Mn-10
- Molecular weight
- 177.06 g/mol
- IUPAC name
- bis(cyclopenta-1,3-diene);manganese
- SMILES
- [CH-]1[C-]=[C-][C-]=[C-]1.[CH-]1[C-]=[C-][C-]=[C-]1.[Mn]
- InChIKey
- HDTBMGOTBXMORT-UHFFFAOYSA-N
- Polar surface area
- 0 Ų
- H-bond donors
- 0
- H-bond acceptors
- 10
- Formal charge
- -10
via PubChem
Wikidata facts
- Subclass of
- chemical compound
- Has part
- carbon
- Mass
- 176.95918096310004
Show 2 more facts
- chemical formula
- C₁₀H₁₀Mn
- canonical SMILES
- [CH-]1[C-]=[C-][C-]=[C-]1.[CH-]1[C-]=[C-][C-]=[C-]1.[Mn]
Sources (2)
via Wikidata · CC0
~1 min read
Encyclopedic overview
3 sectionsContents
- Synthesis and structure
- Reactions
- References
Manganocene or bis(cyclopentadienyl)manganese(II) is an organomanganese compound with the formula [Mn(C5H5)2]n. It is a thermochromic solid that degrades rapidly in air. Although the compound is of little utility, it is often discussed as an example of a metallocene with ionic character.
==Synthesis and structure== It may be prepared in the manner common for other metallocenes, i.e., by reaction of manganese(II) chloride with sodium cyclopentadienide: MnCl2 + 2 CpNa → Cp2Mn + 2 NaCl
Excerpted from Wikipedia’s “manganocene” article, available under the CC BY-SA 4.0 licence.