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marcasite

File:MarcassiteII.jpg · Wikimedia Commons · See Wikimedia Commons

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The mineral marcasite, sometimes called "white iron pyrite", is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both structures contain the disulfide S22− ion, having a short bonding distance between the sulfur atoms. The structures differ in how these di-anions are arranged around the Fe2+ cations. Marcasite is lighter and more brittle than pyrite. Specimens of marcasite often crumble and break up due to the unstable crystal structure.

Key facts

Mineral.name
Marcasite
Mineral.category
Sulfide mineral
Mineral.image
MarcassiteII.jpg
Mineral.imagesize
260px
Mineral.caption
Marcasite with tarnish (8×6 cm)
Mineral.formula
FeS2
Mineral.IMAsymbol
Mrc
Mineral.molweight
119.98 g/mol
Mineral.strunz
2.EB.10a
Mineral.system
Orthorhombic
Mineral.class
Dipyramidal (mmm) H-M symbol: (2/m 2/m 2/m)
Mineral.symmetry
Pnnm
Mineral.unit cell
a 4.436 Å, b 5.414 Å, c 3.381 Å; Z  2
Mineral.color
Tin-white on fresh surface, pale bronze-yellow, darkening on exposure, iridescent tarnish
Mineral.habit
Crystals typically tabular on {010}, curved faces common; stalactitic, reniform, massive; cockscomb and spearhead shapes due to twinning on {101}.
Mineral.twinning
Common and repeated on {101}; less common on {011}.
Mineral.cleavage
Cleavage: {101}, rather distinct; {110} in traces
Mineral.fracture
Irregular/Uneven

via Wikipedia infobox

Wikidata facts

Image
MarcassiteII.jpg
Show 6 more facts
Nickel-Strunz 9th edition (updated 2009)
2.EB.10a
Nickel-Strunz '10th ed', review of (9th ed/ 2009 update)
2.EB.10a
chemical formula
FeS₂
Commons category
Marcasite
IMA Mineral Symbol
Mrc
Strunz 8th edition (series ID, updated)
II/C.07
Sources (2)

via Wikidata · CC0

~7 min read

Article

6 sections
Contents
  • Occurrence
  • Sedimentary marcasite and low pH
  • Varieties and blends
  • Decay
  • References
  • External links

{{Infobox mineral | name = Marcasite | category = Sulfide mineral | boxwidth = | boxbgcolor = | image = MarcassiteII.jpg | imagesize = 260px | caption = Marcasite with tarnish (8×6 cm) | formula = FeS2 | IMAsymbol = Mrc | molweight = 119.98 g/mol | strunz = 2.EB.10a | system = Orthorhombic | class = Dipyramidal (mmm) H-M symbol: (2/m 2/m 2/m) | symmetry = Pnnm | unit cell = a 4.436 Å, b 5.414 Å, c 3.381 Å; Z  2 | color = Tin-white on fresh surface, pale bronze-yellow, darkening on exposure, iridescent tarnish | habit = Crystals typically tabular on {010}, curved faces common; stalactitic, reniform, massive; cockscomb and spearhead shapes due to twinning on {101}. | twinning = Common and repeated on {101}; less common on {011}. | cleavage = Cleavage: {101}, rather distinct; {110} in traces | fracture = Irregular/Uneven | tenacity = Brittle | mohs = 6–6.5 | luster = Metallic | polish = | refractive = | opticalprop = | birefringence = | dispersion = | pleochroism = [100] creamy white; [010] light yellowish white; [001] white with rose-brown tint. Anisotropism: Very strong, yellow through pale green to dark green | absorption = | streak = Dark-grey to black. | gravity = 4.875 calculated, 4.887 measured | density = | melt = | fusibility = | diagnostic = | solubility = | diaphaneity = Opaque | other = | references = }} The mineral marcasite, sometimes called "white iron pyrite", is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both structures contain the disulfide S22− ion, having a short bonding distance between the sulfur atoms. The structures differ in how these di-anions are arranged around the Fe2+ cations. Marcasite is lighter and more brittle than pyrite. Specimens of marcasite often crumble and break up due to the unstable crystal structure.

On fresh surfaces, it is pale yellow to almost white and has a bright metallic luster. It tarnishes to a yellowish or brownish color and gives a black streak. It is a brittle material that cannot be scratched with a knife. The thin, flat, tabular crystals, when joined in groups, are called "cockscombs".

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