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methylenation

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In organic chemistry, methylenation is a chemical reaction that inserts a methylene () group into a chemical compound:

~4 min read

Encyclopedic overview

6 sections
Contents
  • Methods
  • Methylene Insertion into Alkanes
  • Methylene-for-oxo reactions
  • Methylenation adjacent to carbonyl groups
  • Other approaches
  • References

In organic chemistry, methylenation is a chemical reaction that inserts a methylene () group into a chemical compound: \ce{A-B} \longrightarrow \ce{A}{\color{red}\ce{-CH2 -}}\ce{B}

In a related sense, it also describes a process in which a divalent group of a starting material is removed and replaced with a terminal CH2 group: \ce{A=E} \longrightarrow \ce{A}{\color{red}\ce{=CH2}}

Excerpted from Wikipedia’s “methylenation” article, available under the CC BY-SA 4.0 licence.

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