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pentaborane(9)

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Also known as pentaboron nonahydride, nonahydropentaborane, (2,3-muH),(2,5-muH),(3,4-muH),(4,5-muH)-nido-pentaborane(9), pentaborane

Pentaborane(9) is an inorganic compound with the formula . It is one of the most common boron hydride clusters, although it is a highly reactive compound. Because of its high reactivity with oxygen, it was once evaluated as rocket or jet fuel. Like many of the smaller boron hydrides, pentaborane is colourless, diamagnetic, and volatile. It is related to pentaborane(11) ().

Wikidata facts

Mass
64.116959
Show 15 more facts
electric dipole moment
2.13
chemical formula
B₅H₉
canonical SMILES
[BH]123[BH]456[BH]17([BH]28([BH]34([H]5)[H]8)[H]7)[H]6
NIOSH Pocket Guide ID
0481
density
0.62
immediately dangerous to life or health
2.58
melting point
-46.6
boiling point
60
vapor pressure
171
flash point
86
lower flammable limit
0.42
ionization energy
9.9
time-weighted average exposure limit
0.01
short-term exposure limit
0.03
Commons category
Pentaborane(9)
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6 sections
Contents
  • Structure, synthesis, properties
  • Reactions
  • History of its use as a fuel
  • Safety
  • See also
  • References

Pentaborane(9) is an inorganic compound with the formula . It is one of the most common boron hydride clusters, although it is a highly reactive compound. Because of its high reactivity with oxygen, it was once evaluated as rocket or jet fuel. Like many of the smaller boron hydrides, pentaborane is colourless, diamagnetic, and volatile. It is related to pentaborane(11) ().

==Structure, synthesis, properties== Its structure is that of five atoms of boron arranged in a square pyramid. Each boron has a terminal hydride ligand and four hydrides span the edges of the base of the pyramid. It is classified as a nido cage.

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