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Raman scattering

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Raman scattering

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Also known as Raman effect

theory by India's Nobel laureate and Bharat Ratna awardee C.V. Raman

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Setup Raman Spectroscopy adapted from Thomas Schmid and Petra Dariz in Heritage 2(2) (2019) 1662-1683.png
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Raman spectroscopy
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Category:Raman scattering
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Encyclopedic overview

In chemistry and physics, Raman scattering or the Raman effect (/ˈrɑːmən/) is the inelastic scattering of photons by matter, meaning that there is both an exchange of energy and a change in the light's direction. Typically this effect involves vibrational energy being gained by a molecule as incident photons from a visible laser are shifted to lower energy. This is called normal Stokes-Raman scattering.

Light has a certain probability of being scattered by a material. When photons are scattered, most of them are elastically scattered (Rayleigh scattering), such that the scattered photons have the same energy (frequency, wavelength, and therefore color) as the incident photons, but different direction. Rayleigh scattering usually has an intensity in the range 0.1% to 0.01% relative to that of a radiation source. An even smaller fraction of the scattered photons (about 1 in a million) can be scattered inelastically, with the scattered photons having an energy different (usually lower) from those of the incident photons—these are Raman scattered photons. Because of conservation of energy, the material either gains or loses energy in the process.

Excerpted from Wikipedia’s “Raman scattering” article, available under the CC BY-SA 4.0 licence.

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