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thiol

File:Mercapto_Group_General_Formulae.png · Wikimedia Commons · See Wikimedia Commons

EntityQ220410· pop 57· linked from 908 articles

Also known as mercaptan, Sulfhydryl Compounds, Sulfhydryl Compound

thumb|upright=0.5|right|Thiol with a sulfhydryl group.

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A thiol is a type of organic compound that contains a sulfur atom bonded to a hydrogen atom, giving it unique chemical properties. Thiols are important in biological systems and industrial chemistry because this sulfur-hydrogen group makes them reactive and useful for various chemical processes and functions in living organisms.

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Commons category
Thiols
canonical SMILES
S[*]
CXSMILES
S[*] |$;R$|
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~17 min read

Article

28 sections
Contents
  • Nomenclature
  • Physical properties
  • Odor
  • Boiling points and solubility
  • Structure and bonding
  • Characterization
  • Preparation
  • Laboratory methods
  • Classes of thiols
  • Alkyl and aryl thiols
  • Dithiols
  • Unsaturated thiols
  • Thioalcohols
  • Thiol-carboxylic acids
  • Aminothiols
  • Reactions
  • Acidity
  • ''S''-Based nucleophilicity
  • Redox
  • Metal ion complexation
  • Thiyl radicals
  • Biological importance
  • Cysteine and cystine
  • Cofactors
  • Drugs
  • See also
  • References
  • External links

thumb|upright=0.5|right|Thiol with a sulfhydryl group.

In organic chemistry, a thiol (; ), or thiol derivative, is any organosulfur compound of the form , where R represents an alkyl or other organic substituent. The functional group itself is referred to as either a thiol group or a sulfhydryl group, or a sulfanyl group. Thiols are the sulfur analogue of alcohols (that is, sulfur takes the place of oxygen in the hydroxyl () group of an alcohol), and the word is a blend of "thio-" with "alcohol".

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