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Triazane is an inorganic compound with the chemical formula or . Triazane is the third simplest acyclic azane after ammonia and hydrazine. It can be synthesized from hydrazine but is unstable and cannot be isolated in the free base form, only as salt forms such as triazanium sulfate. Attempts to convert triazanium salts to the free base release only diazene and ammonia. Triazane has been stabilized as a complex ion with zeolitic silver structures. Triazane has also been synthesized in electron-irradiated ammonia ices and detected as a stable gas-phase product after sublimation.

Wikidata facts

Mass
47.048347
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canonical SMILES
NNN
chemical formula
H₅N₃
Commons category
Triazane
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Contents
  • Compounds containing the triazane skeleton
  • References
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Triazane is an inorganic compound with the chemical formula or . Triazane is the third simplest acyclic azane after ammonia and hydrazine. It can be synthesized from hydrazine but is unstable and cannot be isolated in the free base form, only as salt forms such as triazanium sulfate. Attempts to convert triazanium salts to the free base release only diazene and ammonia. Triazane has been stabilized as a complex ion with zeolitic silver structures. Triazane has also been synthesized in electron-irradiated ammonia ices and detected as a stable gas-phase product after sublimation.

==Compounds containing the triazane skeleton== Several compounds containing the triazane skeleton are known, including 1-methyl-1-nitrosohydrazine (), produced from the solventless reaction of methylhydrazine () and an alkyl nitrite (R−O−N=O):

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