Biferrocene
Sign in to saveBiferrocene is the organometallic compound with the formula [(C5H5)Fe(C5H4)]2. It is the product of the formal dehydrocoupling of ferrocene, analogous the relationship between biphenyl and benzene. It is an orange, air-stable solid that is soluble in nonpolar organic solvents.
Wikidata facts
- Mass
- 370.01511421528
Show 2 more facts
- chemical formula
- C₂₀H₁₈Fe₂
- canonical SMILES
- [CH-]1[CH-][CH-][C-]([CH-]1)[C-]2C=CC=C2.[CH-]1C=CC=C1.[CH-]1C=CC=C1.[Fe].[Fe]
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4 sectionsContents
- Reactions
- Derivatives
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Biferrocene is the organometallic compound with the formula [(C5H5)Fe(C5H4)]2. It is the product of the formal dehydrocoupling of ferrocene, analogous the relationship between biphenyl and benzene. It is an orange, air-stable solid that is soluble in nonpolar organic solvents.
Biferrocene can be prepared by the Ullmann coupling of iodoferrocene. Its one-electron oxidized derivative [(C5H5)Fe(C5H4)]2+ attracted attention as a prototypical mixed-valence compound.