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hydrotalcite

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Hydrotalcite, or formerly also völknerite, is a layered double hydroxide (LDH) of general formula , whose name is derived from its resemblance with talc and its high water content. Multiple structures containing loosely bound carbonate () ions exist. The easily exchangeable carbonates enable applications of the mineral in wastewater treatment and the immobilisation of radioactive waste after nuclear fuel reprocessing.

Key facts

Mineral.name
Hydrotalcite
Mineral.category
Carbonate mineral
Mineral.image
Hydrotalcite-200667.jpg
Mineral.imagesize
260px
Mineral.caption
Hydrotalcite with serpentine, Snarum, Modum, Buskerud, Norway. Size: 8.4 × 5.2 × 4.1 cm
Mineral.IMAsymbol
Htc
Mineral.strunz
5.DA.50
Mineral.system
3R polytype: Trigonal 2H polytype: Hexagonal
Mineral.class
3R polytype: Hexagonal scalenohedral (m) H-M symbol: ( 2/m) 2H polytype: Dihexagonal dipyramidal (6/mmm)
Mineral.symmetry
Rm
Mineral.unit cell
a = 3.065 Å, c = 23.07 Å; Z = 3
Mineral.color
White with possible brownish tint
Mineral.habit
Subhedral platey crystals, lamellar-fibrous, rarely euhedral prismatic; commonly foliated, massive
Mineral.cleavage
{0001}, perfect
Mineral.tenacity
Flexible, not elastic
Mineral.mohs
2
Mineral.luster
Satiny to greasy or waxy
Mineral.streak
White

via Wikipedia infobox

Wikidata facts

Named after
talc
Image
Hydrotalcite-200667.jpg
Show 8 more facts
Strunz 8th edition (series ID, updated)
Vb/D.02b
Nickel-Strunz '10th ed', review of (9th ed/ 2009 update)
5.DA.50
Nickel-Strunz 9th edition (updated 2009)
5.DA.50
Commons category
Hydrotalcite
streak color
white
IMA Mineral Symbol
Htc
chemical formula
Mg₆Al₂(CO₃)(OH)₁₆ * 4H₂O
Sources (2)

via Wikidata · CC0

~4 min read

Encyclopedic overview

9 sections
Contents
  • Structure and discovery
  • Applications
  • Anion exchange
  • Wastewater treatment
  • Anion getter for nuclear waste disposal
  • Medical
  • See also
  • References
  • Further reading

{{Infobox mineral | name = Hydrotalcite | category = Carbonate mineral | image = Hydrotalcite-200667.jpg | imagesize = 260px | caption = Hydrotalcite with serpentine, Snarum, Modum, Buskerud, Norway. Size: 8.4 × 5.2 × 4.1 cm | formula = | IMAsymbol = Htc | molweight = | strunz = 5.DA.50 | dana = | system = 3R polytype: Trigonal 2H polytype: Hexagonal | class = 3R polytype: Hexagonal scalenohedral (m) H-M symbol: ( 2/m) 2H polytype: Dihexagonal dipyramidal (6/mmm) | symmetry = Rm | unit cell = a = 3.065 Å, c = 23.07 Å; Z = 3 | color = White with possible brownish tint | colour = | habit = Subhedral platey crystals, lamellar-fibrous, rarely euhedral prismatic; commonly foliated, massive | twinning = | cleavage = {0001}, perfect | fracture = | tenacity = Flexible, not elastic | mohs = 2 | luster = Satiny to greasy or waxy | streak = White | diaphaneity = Transparent | gravity = 2.03–2.09 | density = | polish = | opticalprop = Uniaxial (−) | refractive = nω = 1.511 – 1.531 nε = 1.495 – 1.529 | birefringence = δ = 0.016 | pleochroism = | 2V = | dispersion = | extinction = | length fast/slow = | fluorescence= | absorption = | melt = | fusibility = | diagnostic = | solubility = | other = Greasy feel | alteration = | references = }} Hydrotalcite, or formerly also völknerite, is a layered double hydroxide (LDH) of general formula , whose name is derived from its resemblance with talc and its high water content. Multiple structures containing loosely bound carbonate () ions exist. The easily exchangeable carbonates enable applications of the mineral in wastewater treatment and the immobilisation of radioactive waste after nuclear fuel reprocessing.

== Structure and discovery == It was first described in 1842 for an occurrence in a serpentine–magnesite deposit in Snarum, Modum, Buskerud, Norway. It occurs as an alteration mineral in serpentinite in association with serpentine, dolomite and hematite. The layers of the structure stack in multiple ways, to produce a 3-layer rhombohedral structure (3R polytype), or a 2-layer hexagonal structure (2H polytype) formerly known as manasseite. The two polytypes are often intergrown.

Excerpted from Wikipedia’s “hydrotalcite” article, available under the CC BY-SA 4.0 licence.