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isorhamnetin

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isorhamnetin

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Also known as 3,5,7,4'-tetrahydroxy-3'-methoxyflavone, 3,5,7-trihydroxy-2-(4-hydroxy-3-methoxyphenyl)-4H-benzopyran-4-one, quercetin 3'-methyl ether, 3-methylquercetin, isorhamnetol, 3,4',5,7-tetrahydroxy-3'-methoxy-Flavone, 3'-methoxyquercetin, 3-methylquercetine

Isorhamnetin is an O-methylated flavon-ol from the class of flavonoids. A common food source of this 3'-methoxylated derivative of quercetin and its glucoside conjugates are pungent yellow or red onions, in which it is a minor pigment, quercetin-3,4'-diglucoside and quercetin-4'-glucoside and the aglycone quercetin being the major pigments. Pears, olive oil, wine and tomato sauce are rich in isorhamnetin. Almond skin is a rich source of isorhamnetin-3-O-rutinoside and isorhamnetin-3-O-glucoside, in some cultivars they comprise 75% of the polyphenol content, the total of which can exceed 10 mg/

Chemical data

Formula
C16H12O7
Molecular weight
316.26 g/mol
IUPAC name
3,5,7-trihydroxy-2-(4-hydroxy-3-methoxyphenyl)chromen-4-one
SMILES
COC1=C(C=CC(=C1)C2=C(C(=O)C3=C(C=C(C=C3O2)O)O)O)O
InChIKey
IZQSVPBOUDKVDZ-UHFFFAOYSA-N
XLogP
1.9
Polar surface area
116 Ų
H-bond donors
4
H-bond acceptors
7
Formal charge
0

via PubChem

Drug data · ChEMBL

Molecule type
Small molecule

via ChEMBL · EBI

Wikidata facts

Subclass of
flavone
Mass
316.058303
Show 4 more facts
chemical formula
C₁₆H₁₂O₇
canonical SMILES
COC1=C(C=CC(=C1)C2=C(C(=O)C3=C(C=C(C=C3O2)O)O)O)O
has characteristic
bitterness
Sources (3)

via Wikidata · CC0

~2 min read

Encyclopedic overview

5 sections
Contents
  • Metabolism
  • Glycosides
  • See also
  • References
  • External links

Isorhamnetin is an O-methylated flavon-ol from the class of flavonoids. A common food source of this 3'-methoxylated derivative of quercetin and its glucoside conjugates are pungent yellow or red onions, in which it is a minor pigment, quercetin-3,4'-diglucoside and quercetin-4'-glucoside and the aglycone quercetin being the major pigments. Pears, olive oil, wine and tomato sauce are rich in isorhamnetin. Almond skin is a rich source of isorhamnetin-3-O-rutinoside and isorhamnetin-3-O-glucoside, in some cultivars they comprise 75% of the polyphenol content, the total of which can exceed 10 mg/100 gram almond. Others sources include the spice, herbal medicinal and psychoactive Mexican tarragon (Tagetes lucida), which is described as accumulating isorhamnetin and its 7-O-glucoside derivate. Nopal (Opuntia ficus-indica (L.)) is also a good source of isorhamnetin, which can be extracted by supercritical fluid extraction assisted by enzymes.

==Metabolism== The enzyme quercetin 3-O-methyltransferase uses S-adenosyl methionine and quercetin to produce S-adenosylhomocysteine and isorhamnetin.

Excerpted from Wikipedia’s “isorhamnetin” article, available under the CC BY-SA 4.0 licence.