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partial pressure

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partial pressure

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hypothetical pressure of gas if it alone occupied the volume of the mixture at the same temperature

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The atmospheric pressure is roughly equal to the sum of partial pressures of constituent gases – oxygen, nitrogen, argon, water vapor, carbon dioxide, etc.

In a mixture of gases, each constituent gas has a partial pressure which is the notional pressure of that constituent gas as if it alone occupied the entire volume of the original mixture at the same temperature. The total pressure of an ideal gas mixture is the sum of the partial pressures of the gases in the mixture (Dalton's Law). Partial pressure can be highlighted with a thought experiment using semipermeable pistons, as underlined by Boltzmann, Gibbs and Planck.

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