Structure via PubChem · Public domain (PubChem)
thiepine
Sign in to saveAlso known as thiepin
In organic chemistry, thiepine (or thiepin) is an unsaturated seven-membered heterocyclic compound, with six carbon atoms and one sulfur atom. The parent compound, C6H6S is unstable and is predicted to be antiaromatic. Bulky derivatives have been isolated and shown by X-ray crystallography to have nonplanar C6S ring.
Chemical data
- Formula
- C6H6S
- Molecular weight
- 110.18 g/mol
- IUPAC name
- thiepine
- SMILES
- C1=CC=CSC=C1
- InChIKey
- BISQTCXKVNCDDA-UHFFFAOYSA-N
- XLogP
- 2.2
- Polar surface area
- 25.3 Ų
- H-bond donors
- 0
- H-bond acceptors
- 1
- Formal charge
- 0
via PubChem
Wikidata facts
- Mass
- 110.019021
Show 3 more facts
- chemical formula
- C₆H₆S
- canonical SMILES
- C1=CC=CSC=C1
- Commons category
- Thiepine
Sources (2)
via Wikidata · CC0
~1 min read
Article
3 sectionsContents
- See also
- References
- External links
In organic chemistry, thiepine (or thiepin) is an unsaturated seven-membered heterocyclic compound, with six carbon atoms and one sulfur atom. The parent compound, C6H6S is unstable and is predicted to be antiaromatic. Bulky derivatives have been isolated and shown by X-ray crystallography to have nonplanar C6S ring.
Computational studies suggest that thiepine would eliminate a sulfur atom to form benzene. The intermediate is this process is the bicycle thianorcaradiene. In the complex with (η4-C6H6S)Fe(CO)3, the ring is stable.