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trimethylgallium
Sign in to saveTrimethylgallium, often abbreviated to TMG or TMGa, is the organogallium compound with the formula Ga(CH3)3. It is a colorless, pyrophoric liquid. Unlike trimethylaluminium, TMG adopts a monomeric structure. When examined in detail, the monomeric units are clearly linked by multiple weak Ga---C interactions, reminiscent of the situation for trimethylindium.
Chemical data
- Formula
- C3H9Ga
- Molecular weight
- 114.83 g/mol
- IUPAC name
- trimethylgallane
- SMILES
- C[Ga](C)C
- InChIKey
- XCZXGTMEAKBVPV-UHFFFAOYSA-N
- Polar surface area
- 0 Ų
- H-bond donors
- 0
- H-bond acceptors
- 0
- Formal charge
- 0
via PubChem
Wikidata facts
- Subclass of
- chemical compound
- Has part
- carbon
- Mass
- 113.995999
Show 4 more facts
- canonical SMILES
- C[Ga](C)C
- chemical formula
- C₃H₉Ga
- Commons category
- Trimethylgallium
- boiling point
- 55.7
via Wikidata · CC0
~2 min read
Encyclopedic overview
3 sectionsContents
- Preparation
- Applications
- References
Trimethylgallium, often abbreviated to TMG or TMGa, is the organogallium compound with the formula Ga(CH3)3. It is a colorless, pyrophoric liquid. Unlike trimethylaluminium, TMG adopts a monomeric structure. When examined in detail, the monomeric units are clearly linked by multiple weak Ga---C interactions, reminiscent of the situation for trimethylindium.
==Preparation== Two forms of TMG are typically investigated: Lewis base adducts or TMG itself. All are prepared by reactions of gallium trichloride with various methylating agents. When the methylation is conducted with methylmagnesium iodide in diethyl ether, the product is the poorly volatile diethyl ether adduct. As noted by TMG discoverers Kraus and Toonder in 1933, the ether ligand is not readily lost, although it may be displaced with liquid ammonia. When the alkylation is conducted with methyl lithium in the presence of a tertiary phosphine the air-stable phosphine adduct is obtained:
Excerpted from Wikipedia’s “trimethylgallium” article, available under the CC BY-SA 4.0 licence.