vanadocene
Sign in to saveVanadocene, bis(η5-cyclopentadienyl) vanadium, is the organometallic compound with the formula V(C5H5)2, commonly abbreviated Cp2V. It is a violet crystalline, paramagnetic solid. Vanadocene has relatively limited practical use, but it has been extensively studied.
Wikidata facts
- Mass
- 181.02550129946002
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- canonical SMILES
- [CH-]1[CH-][CH-][CH-][CH-]1.[CH-]1C=CC=C1.[V]
- chemical formula
- C₁₀H₁₀V⁶⁻
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Article
5 sectionsContents
- Structure and bonding
- Preparation
- Properties
- Related compounds
- References
Vanadocene, bis(η5-cyclopentadienyl) vanadium, is the organometallic compound with the formula V(C5H5)2, commonly abbreviated Cp2V. It is a violet crystalline, paramagnetic solid. Vanadocene has relatively limited practical use, but it has been extensively studied.
== Structure and bonding == V(C5H5)2 is a metallocene, a class of organometallic compounds that typically have a metal ion sandwiched between two cyclopentadienyl rings. In the solid state, the molecule has D5d symmetry. The vanadium(II) center resides equidistant between the center of the two cyclopentadienyl rings at a crystallographic center of inversion. The average V-C bond distance is 226 pm. The Cp rings of vanadocene are dynamically disordered at temperatures above 170 K and are only fully ordered at 108 K.