ammonolysis
Sign in to saveIn chemistry, ammonolysis (/am·mo·nol·y·sis/) is the process of splitting ammonia into NH2- + H+. Ammonolysis reactions can be conducted with organic compounds to produce amines (molecules containing a nitrogen atom with a lone pair, :N), or with inorganic compounds to produce nitrides. This reaction is analogous to hydrolysis in which water molecules are split. Similar to water, liquid ammonia also undergoes auto-ionization, {2 NH3 ⇌ NH4+ + NH2- }, where the rate constant is k = 1.9 × 10−38.
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7 sectionsContents
- Organic synthesis
- Mechanism: Ammonolysis of Esters
- Of haloalkanes
- Of alcohols
- Of carbonyl compounds
- Inorganic synthesis
- References
In chemistry, ammonolysis (/am·mo·nol·y·sis/) is the process of splitting ammonia into NH2- + H+. Ammonolysis reactions can be conducted with organic compounds to produce amines (molecules containing a nitrogen atom with a lone pair, :N), or with inorganic compounds to produce nitrides. This reaction is analogous to hydrolysis in which water molecules are split. Similar to water, liquid ammonia also undergoes auto-ionization, {2 NH3 ⇌ NH4+ + NH2- }, where the rate constant is k = 1.9 × 10−38.
Organic compounds such as alkyl halides, hydroxyls (hydroxyl nitriles and carbohydrates), carbonyl (aldehydes/ketones/esters/alcohols), and sulfur (sulfonyl derivatives) can all undergo ammonolysis in liquid ammonia.