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Lewisite

Structure via PubChem · Public domain (PubChem)

EntityQ407502· pop 36· linked from 298 articles

Also known as L, (2-chlorovinyl)dichloro-arsine, dichloro(2-chlorovinyl)-arsine, (2-chloroethenyl)-arsenous dichloride, (2-chloroethenyl)-arsonous dichloride, (2-chloroethenyl)arsonous dichloride, (2-chlorovinyl) dichloroarsine, (e)-lewisite 1

Lewisite (L) (A-243) is an organoarsenic compound. It was once manufactured in the United States, Japan, Germany and the Soviet Union for use as a chemical weapon, acting as a vesicant (blister agent) and lung irritant. Although colorless and odorless in its pure form, impure samples of lewisite are a yellow, brown, violet-black, green, or amber oily liquid with a distinctive odor that has been described as similar to geraniums.

Chemical data

Formula
C2H2AsCl3
Molecular weight
207.31 g/mol
IUPAC name
dichloro-[(E)-2-chloroethenyl]arsane
SMILES
C(=C/[As](Cl)Cl)\Cl
InChIKey
GIKLTQKNOXNBNY-OWOJBTEDSA-N
Polar surface area
0 Ų
H-bond donors
0
H-bond acceptors
0
Formal charge
0

via PubChem

Wikidata facts

Mass
205.844
Show 8 more facts
chemical formula
C₂H₂AsCl₃
boiling point
190
melting point
0.1
density
1.89
canonical SMILES
C(=C[As](Cl)Cl)Cl
isomeric SMILES
C(=C/[As](Cl)Cl)\Cl
refractive index
1.6076
Commons category
Lewisite
Sources (5)

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~12 min read

Article

10 sections
Contents
  • Chemical reactions
  • Applications
  • Mechanism of action
  • Treatment
  • Long-term effects
  • Chemical composition
  • History
  • Controversy over Japanese deposits of lewisite in China
  • See also
  • References

Lewisite (L) (A-243) is an organoarsenic compound. It was once manufactured in the United States, Japan, Germany and the Soviet Union for use as a chemical weapon, acting as a vesicant (blister agent) and lung irritant. Although colorless and odorless in its pure form, impure samples of lewisite are a yellow, brown, violet-black, green, or amber oily liquid with a distinctive odor that has been described as similar to geraniums.

Lewisite is named after the US chemist and soldier Winford Lee Lewis (1878–1943). Lewisite has no applications other than use as a chemical weapon, with a chemist from the United States Army's chemical warfare laboratories stating that "no one has ever found any use for the compound".

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