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molybdate
EntityQ3273039· pop 19· linked from 115 articles

Also known as molybdates

thumb|150px|Structure of molybdate thumb|150px|3D model of the molybdate ion

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Molybdates
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13 sections
Contents
  • Examples of molybdate anions
  • Structure of molybdate anions
  • Equilibrium in aqueous solution
  • Peroxomolybdates
  • Tetrathiomolybdate
  • Industrial uses
  • Catalysis
  • Corrosion inhibitors
  • Supercapacitors
  • Medicine
  • Other
  • Natural gems
  • References

thumb|150px|Structure of molybdate thumb|150px|3D model of the molybdate ion

In chemistry, a molybdate is a compound containing an oxyanion with molybdenum in its highest oxidation state of +6: . Molybdenum can form a very large range of such oxyanions, which can be discrete structures or polymeric extended structures, although the latter are only found in the solid state. The larger oxyanions are members of group of compounds termed polyoxometalates, and because they contain only one type of metal atom are often called isopolymetalates. The discrete molybdenum oxyanions range in size from the simplest , found in potassium molybdate up to extremely large structures found in isopoly-molybdenum blues that contain for example 154 Mo atoms. The behaviour of molybdenum is different from the other elements in group 6. Chromium only forms the chromates, , , and ions which are all based on tetrahedral chromium. Tungsten is similar to molybdenum and forms many tungstates containing 6 coordinate tungsten.

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