triethylsilane
Sign in to saveTriethylsilane , also known as TES or triethylsilicon hydride, is the organosilicon compound with the formula (C2H5)3SiH. It is a trialkylsilane. The Si-H bond is reactive.
Research
233 papers- A bioorthogonal system reveals antitumour immune function of pyroptosis.Nature · 2020
- Mild and Chemoselective Triethylsilane-Mediated Debenzylation for Phosphate Synthesis.Organic letters · 2025
- Pd-C-induced catalytic transfer hydrogenation with triethylsilane.The Journal of organic chemistry · 2007
- Regioselective Reductive Opening of Benzylidene Acetals with Dichlorophenylborane/Triethylsilane: Previously Unreported Side Reactions and How to Prevent Them.The Journal of organic chemistry · 2022
- Synthesis of Natural and Sugar-Modified Nucleosides Using the Iodine/Triethylsilane System as N-Glycosidation Promoter.International journal of molecular sciences · 2024
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Wikidata facts
- Mass
- 116.102
Show 4 more facts
- chemical formula
- C₆H₁₆Si
- canonical SMILES
- CC[SiH](CC)CC
- melting point
- -157.0
- Commons category
- Triethylsilane
via Wikidata · CC0
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Article
3 sectionsContents
- Organic chemistry
- Additional reading
- References
Triethylsilane , also known as TES or triethylsilicon hydride, is the organosilicon compound with the formula (C2H5)3SiH. It is a trialkylsilane. The Si-H bond is reactive.
It was first discovered by Albert Ladenburg in 1872 among the products of reduction of tetraethyl orthosilicate with sodium and diethylzinc. He also prepared it by a stepwise reduction via ethoxytriethylsilane and named it silicoheptyl hydride, reflecting the idea of a silicon compound analogous to a seven-carbon hydrocarbon. This colorless liquid finds occasion use in organic synthesis. As one of the simplest trialkylsilanes that is a liquid at room temperature, triethylsilane is often used in studies of hydrosilylation catalysis.